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Abstract

Methanofullerenes from Cycloaddition to C60

Author(s): Jeff Hardy

The [2+1] cycloaddition process is the most common form of fullerene core functionalization. The reactions that result in methanofullerenes are the most promising of these. They're made in two ways: the Bingel process of nucleophiliccyclopropanation and the thermal addition of diazo compounds. The key cyclopropanating agents used in the synthesis of monosubstitutedmethanofullerenes, as well as the optimal conditions and mechanism of the [2+1] cycloaddition, as well as the functional application of the target products, are discussed


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