Original Article
Int. J. Chem. Sci, Volume: 17( 1) DOI: 10.21767/0972-768X.1000306

Adsorption of Cd2+ ions from Synthetic Water by Magnetic Core Shell Nanocomposite SiO2/FeO/Fe3O4/SiO2

*Correspondence:
Elfiky AA
Department of Applications, Egyptian Petroleum Research Institute (EPRI)
Ahmed El-Zomer, Nasr City, P.O. Box. No, Cairo, Egypt
Tel: +202-22747847
E-mail: [email protected]

Received: March 06, 2019; Accepted: March 30, 2019; Published: April 05, 2019

Citation:Elfiky AA, Fathy M, Eltorgoman AM, et al. Adsorption of Cd2+ ions from synthetic water by Magnetic Core Shell Nanocomposite SiO2/FeO/ Fe3O4/ SiO2. Int J Chem Sci. 2019;17(1):306

Abstract

The magnetic silica core shell nanocomposite SiO2/FeO/Fe3O4/SiO2, which designated by (AS/Fe/AS), was synthesized and characterized by chemical analyses, FTIR, XRD, SEM, HR-TEM. The magnetic properties of (AS/Fe/AS) as a function of magnetic field, temperature, and time was measured using Vibrating Sample Magnetometer (VSM). Finally, the chemical purity and their stoichiometry of magnetic core shell SiO2 /FeO/ Fe3O4/ SiO2 (AS/Fe/AS) were done by Energy-dispersive X-ray spectroscopy (EDX). Also, the kinetic and isotherm studied were carried out by considering some important factors such as temperature, time and initial metal concentration on the adsorption capacity of (AS/Fe/AS) to remove Cd2+ ions from synthetic polluted water. The result confirms that we have successfully synthesized a new high-purity magnetite nanocomposite (AS/Fe/AS), which characterized by the presence of highly saturated magnetization and intensively black color. Also, we found that the kinetic and isotherm studied revealed that the adsorption kinetics and equilibrium data were best fitted by pseudo-second order kinetic model and Freundlich adsorption isotherm.

Keywords

Organic pollutants; Nanocomposite; Spectroscopy; Nanoparticles; Metal contamination

Introduction

Increasing the discharge of industrial waste water containing a large amount of heavy metals such as copper (II), Cd (II) and Pb (II) and organic pollutants in water or soil, is one of the biggest problems facing our societies at present, which in turn threat the environment and public health, because of their severe toxicity, if not discharged without proper treatment [1]. Cadmium is one of the most toxic elements that cause serious mutilation to the reproductive system, kidneys, liver, nervous system and the brain [2]. The maximum daily detection of cadmium from all sources (water, food and air) ranges from 1.0 to 1.2 μg/kg of body mass. In addition, the permissible limit of cadmium in drinking water must be not exceeded than 0.005 (mg/L). Thereby, the periodical examination must be applying on the water treatment equipment to ensure that the permissible limit of feed water conditions and equipment capacity are not exceeded [3]. Many methods had been used to remove heavy metals, such as chemical precipitation [4], electro-flotation, ion-exchange and reverse osmosis; unfortunately, all of these methods are uneconomic in many developing countries. Meanwhile, the adsorption method is characterized by being more efficient, relatively economical, flexibility of design, ease of operation and the secondary waste such as sludge did not form. A wide range of adsorbents such as activated carbons, metal oxide composite, miso pours silica nanoparticle, polymer composite, and mixed organic inorganic nanocomposite have been developed and tested as adsorbents to remove Cd2+ ions and others from wastewaters [5,6]. The magnetic nanoparticles such as Fe2 and its oxide (Fe3O4), showed a high metal adsorption capacity, high dispersion degree and super para magnetism behavior compared to their bulk form [7]. Therefore, and due to their properties, they can be applied on a wide field such as electronics, biotechnology, medicine, heavy oil upgrading, air pollution, and for water treatment [8].

Magnetic core shell silica nanocomposite is currently interest due to their potential applications in water treatment and remediation, hetero- and photo catalysis, optics and ultra-high-density magnetic storage. In addition, the silica Nanocomposite that having distinct core and shell magnetic phases [9], are very actively being investigated for magnetic sorbents and other potential applications such as removal of heavy metals from polluted water [6]. Silica-based magnetic nanoparticles have been various advantages choosing over for encapsulating magnetic nano-particles. Various silica particles with different mesh size have been used for the immobilization of important enzyme and bio-catalysis in organic media. Silica immobilized enzymes have been used for the synthesis of flavor esters and various medically important esters in organic solvents. It exposes silanol surface groups which can be derivative with a number of functional groups. It has optical transparency. It can prevent luminescence quenching by providing barrier in between the fluorophore and magnetic core. Due to their degradation stability, biocompatibility and hydrophilic character makes its application in environment and biomedical. They can be made by spray-drying, aerosol pyrolysis, sol–gel processes, and micro emulsion polymerization. A graphic representation of silica-based magnetic nano-particles has been depicted in FIG. 1. Different magnetic nano-composites made with their applications in previous studies are given in the reference [10,11].

organic-chemistry-nano-particles

FIG. 1. Mechanism of silica-based magnetic nano-particles.

We aim to synthesize of magnetic core shell nanocomposite SiO2/FeO/Fe3O4/ SiO2 (AS/Fe/AS), via mixing of iron oxide with silica, to adsorb Cd2+ ions from synthetic polluted water, then characterize the prepared (AS/Fe/AS) by FTIR spectroscopy, XRD, TGA, chemical analyses, and by SEM, HR-TEM electron microscopy. Also, we aim to study the adsorption capacity of Cd2+ ions onto AS/Fe/AS at different contact time, pH, adsorbent dose and initial Cd2+ions concentration. Finally, we determine the appropriate adsorption isotherm and kinetics parameters of Cd2+ ions onto (AS/Fe/AS).

Experimental Procedure

Materials

Ethanol, cadmium nitrate tetrahydrate and ferric chloride, amorphous silica gel (0.06-0.2 mm, 60A) were all obtained from Sigma-Aldrich. TEOS (Tetraethyl ortho-silicate or tetra-ethoxysilane) is a colorless liquid degrades in water, with chemical formula of Si (OC2H5)4, was obtained from Sigma-Aldrich. The other chemicals that used were analytical grade. The stock cadmium solution was diluted at appropriate proportions, to prepare different initial cadmium concentrations. All glassware was kept overnight in a 10% (v/v) HNO3 solution to prevent laboratory glassware from metal contamination. Stock solutions were prepared daily by dissolving in distilled water.

Preparation of magnetic silica core shell nanocomposite FeO/ Fe3O4/ SiO2 (Fe/AS)

The suspended silica was prepared by distributing 20 g of amorphous silica gel (AS) (0.06-0.2 mm, 60A) in 250 ml distilled water with stirring at 250-300 rpm. The iron chloride solution was prepared by solubilizing of 10 grams of FeCl3 in 50 ml distilled water. Then iron chloride solution was added drop wise with stirring for 20 minutes to the suspended silica, for obtaining the adsorbed magnetic silica composite [12] and was precipitate by adding sodium hydroxide solution then left the suspended solution for 2 hours. 100 ml of 0.3 M NaBH4 was added drop wise to magnetic silica composite with vigorous stirring at 4000 rpm for 40 min, to reduce the trivalent iron oxide producing surface cover zero valent iron (Fe/AS). Then filtrate the precipitate and washed it with 250 to 500 ml distilled water until it becomes neutral, then dried in the oven at 150ºC for 2 hours to obtain calcinated Fe/AS nanocomposite as shown in FIG. 2 [13].

organic-chemistry-magnetic-silica

FIG. 2. Preparation of magnetic silica nanocomposite FeO/Fe3O4/SiO2 (Fe/AS).

Preparation of magnetic core shell SiO2/FeO/ Fe3O4/ SiO2 nanocomposite (AS/Fe/AS)

2 g of the prepared Fe/AS nanocomposite was added to 50 ml of TEOS solubilized in 150 ml ethanol and then precipitate by 0.5% w/v sodium hydroxide solution with stirring at 60°C for one hour and left. The precipitate was washed with distilled water until it becomes neutral and leaves to dry at 80°C to obtain on a dark brown gel, then leave for 1 hour with stirring at room temperature and dried in a muffle furnace. After that, the dark brown gel was calcinated at 200°C for 8 hours for oxidation all the hydroxide Fe (OH)3 and partial oxides to iron oxide Fe3O4 in presence of FeO spots within the latex of magnetite, finally, a black magnetite core shell SiO2/FeO/Fe3O4/SiO2 nono-composite (AS/Fe/AS) was obtained as shown in FIG. 3 [14].

organic-chemistry-core-shell

FIG. 3. Preparation of magnetic core shell SiO2 /FeO/ Fe3O4/ SiO2 (AS/Fe/AS).

Methods of characterization

Chemical structure of the AS/Fe/AS nanocomposite were confirmed by using FTIR (Nicolet IS-10 FT-IR), where X-ray diffraction (XRD) (Shimadzu XRD Model 6000) was used to describe its structure phases and average size. Additionally, the surface morphology (SEM and HR-TEM) were characterized using SEM, Jeol, Model JSM5300 at 15 Kev. The magnetic properties of (AS/Fe/AS) as a function of magnetic field, temperature, and time was measured using BHV-55. Vibrating Sample Magnetometer (VSM). Finally, the elemental analysis or chemical characterization or chemical purity and their stoichiometry of magnetic core shell SiO2/FeO/Fe3O4/SiO2(AS/Fe/AS) were done by Energy-dispersive X-ray spectroscopy (EDX) (EDX, Kevex, Delta Class I).

Adsorption procedure

Adsorption tests were performed in batch-mode according to the procedures described by Fathy and Elsayed [15], and the resulted data were analyzed using both of pseudo-first-order and pseudo-second-order kinetic models as tabulate in TABLE 1. The adsorption capacity and the removal percentage (R%) of Cd2+ ions onto (AS/Fe/AS) were measured at wavelength of 554 nm.

Pseudo-first-order Pseudo-second-order
Models Cd2+ ions Models Cd2+ ions
k 1 (min-1) 0.049 k2 (×10-3g mg-1 min-1) 3.98
qeq (cal) (mg g-1) 20.5 qeq (cal) (mg g-1) 350.9
r2 0.9211 r2 0.9989

TABLE 1. Calculated kinetic parameters for the adsorption of Cd2+ ions onto AS/Fe/AS nanocomposites.

Adsorption isotherms

Adsorption isotherms of AS/Fe/AS nanocomposite were conducted by varying the initial Cd2+ ions concentration from 10 to 300 mg/L at different temperatures (298-345 K) and pH 6.5. The resulted data were analyzed by applying Langmuir and Freundlich isotherm models and were given in TABLE 2.

Isotherm equation Langmuir Isotherm equation Freundlich
Qm (mg g-1) 0.826557 k f 2.037434
KL (L mg-1) 0.007297 n 3.002945
R 2 0.636067 R 2 1

TABLE 2. The calculated Langmuir and Freundlich Isotherm.

Results and Discussion

FTIR analysis

The FTIR spectrum of magnetic silica core shell nanocomposite SiO2/FeO/Fe3O4/SiO2(AS/Fe/AS) which designated by (AS/Fe/AS) is given inFIG. 4 and shows the presence of absorption bands at 3650-3200 cm-1 correspond to O–H stretching vibration mode of Fe–OH bond, with the presence of two bands at approximately 1070, and 600 cm-1, which are assigned to the stretching and bending vibration modes of Si–O–Si surface, respectively, whereas, the band observed at 460 cm-1 is assigned to Fe–O stretching bond. The existence of SiO2 layers in the spectrum of can be realized by the Si–O–Si stretching vibration at 1070 cm-1, as well as the Fe–O–Si stretching vibration at 1250-1050 cm-1. The result confirms the successfully synthesized of new high-purity magnetite nanocomposite (AS/Fe/AS), characterized with the presence of highly saturated magnetization and intensively black color.

organic-chemistry-nanocomposite

FIG. 4. FTIR spectrum of AS/Fe/AS nanocomposite.

Characterization using XRD

Three X-ray diffraction spectrum patterns are shown in FIG. 5 and named by (AS), FeO and (AS/Fe/AS), respectively. The interpretation of these spectra is as follows:

organic-chemistry-magnetic

FIG. 5. The XRD spectrum of amorphous silica particles (AS), Feº, and the prepared magnetic core shell nanocomposite (AS/Fe/AS).

The XRD peak of AS indicated the presence of only amorphous peak characterized with the equivalent Bragg angle at 2θ=21.8º, we may note there are tetragonal a-crystobalite and a small fraction of monoclinic tridymite were obtained [16]. Secondary, the XRD pattern of magnetic Fe3O4 which named by FeO has the spinal structure with characteristic peaks at 2θ=27.47, 31.85°, 45.61° and 56.61° correspond to Fe3O4 crystal plane of (2 2 0), (3 1 1), (4 0 0), (4 2 2), and (5 1 1), respectively (JCPDS Card No. 019-0629), and their nano-crystalline size found around 40 nm as calculate by Scherrer equation.

Finally, the XRD pattern of the prepared magnetic core shell nanocomposite (AS/Fe/AS), exhibit the presence of both Fe3O4 crystal phase and SiO2 amorphous phase [17]. Also, the Fe3O4 crystal structure changed and shifted to lower degree with respect to magnetic nanoparticles after coating with SiO2 mesoporous shell (JCPDS no. 33-1161). This result can be explained by the unequal distribution of magnetic particles on AS/Fe/AS surface, beside the presence of silica sheet on the surface of the magnetic particles, beside the presence of silica particles on the core [18].

Scanning electron microscopy of magnetic nanocomposite (AS/Fe/AS)

SEM image of (AS/Fe/AS) in FIG. 6 indicates that the first homogeneous cover layer of FeO and Fe3O4 were formed on the silica spheres. Also, we can see in the top left image in FIG. 6, the second thin silicon dioxide layer was formed on magnetic iron silica composite. However, the formation of thin silica shells on the nano-FeO/Fe3O4 particles returned rough surface and the resultant products showed nearly wide dispersed spheres 700-1500 μm-sized silica core.

organic-chemistry-nanocomposite

FIG. 6. SEM images of magnetic nanocomposite AS/Fe/AS.

The magnetic properties of the prepared magnetic nanocomposite AS/Fe/AS

The magnetic properties of the prepared FeO and magnetic nanocomposite (AS/Fe/AS) curves were measured using Vibrating Sample Magnetometer (VSM) and presented in FIG. 7. Clearly, the field-dependent magnetization curves of FeO and (AS/Fe/AS) measured at 300 K, exhibited a typical super- paramagnetic and no hysteresis was observed in low fields, otherwise, the magnetic saturation value of FeO and AS/Fe/AS are 9 emu/g and 48 emu/g, respectively, i.e., the sharply decreases of magnetic saturation value of FeO, can be attributed to increase of magnetic oxides and FeO mass. Additionally, as shown in FIG. 6, SiO2/FeO/ Fe3O4/ SiO2 with super paramagnetic characteristic and high magnetization value could quickly respond to external magnetic field and re-disperse in aqueous solution once the external magnetic field was removed and with gentle shaking or sonication.

HR-TEM of magnetic nanocomposite (AS/Fe/AS)

Its observed from the HR-TEM of (AS/Fe/AS) in FIG. 8, that the size of silica nanocomposite coated with shell synthesized from TEOS ranged between 500-600 nm, and our results are very good compatible with the reference [16]. On the other hand, it is clear from the upper lift side on magnified FIG. 7, that the nano-FeO/Fe3O4 core are randomly distributed and their size ranges between 150-200 nm. Also, a thin silica shell was appeared as a smooth surface without any Flexural or aliasing on the surface of nano-FeO/Fe3O4 core, this indicated on the formation of thin layer from SiO2 core–shell with uniform spherical morphology.

organic-chemistry-nano-composite

FIG. 7. VSM of the prepared FeO and magnetic nano-composite AS/Fe/AS at 300 K.

organic-chemistry-morphology-surface

FIG. 8. Particle morphology and surface feature of core shell AS/Fe/AS magnetic nanocomposite.

EDX spectra of magnetic nanocomposite (AS/Fe/AS)

The EDX spectrum given in FIG. 9a shows the presence of Fe and O as the only elementary components of Fe3O4 nanoparticles. EDX spectrum of Fe3O4/SiO2 (FIG. 9b) shows the elemental compositions are (Fe, O and Si) of core-shell nanoparticles. The EDX spectrum of SiO2/FeO/ Fe3O4/ SiO2 (FIG. 9c) shows the elemental compositions are (Fe, Si, O and FeO) of magnetic nanocomposite.

organic-chemistry-spectra

FIG. 9. EDX spectra of (a) Fe3O4, (b) Fe3O4/SiO2 and (cSiO2/FeO/ Fe3O4/ SiO2.

Evaluation of adsorption performance

Effect of adsorbent dose: As shown in FIG. 10, the minimum Cd2+ ions removal, was 53.12% at 0.05 g of nanocomposite, whereas, the maximum Cd2+ ions removal value was 85.52% at 0.25 g of AS/Fe/AS nanocomposite. The increase in adsorption with increasing the amount of meso-porous silica composite dose may be attributed to the fact of the availability of more adsorption sites, i.e., increasing the available surface area to complete the adsorption process [19].

organic-chemistry-adsorption

FIG. 10. Effect of adsorbent dose on the adsorption of Cd2+ ions on the AS/Fe/AS nanocomposite.

Effect of pH

It is known thatCd2+ ions are present in the form of Cd hydroxide in deionized water [20]. It was observed in FIG. 11, at pH 14, the efficiency of Cd2+ ions removal reaches up 90% at Cd2+ ions concentration of 11 mg/L. This phenomena can be explained by, when pH increases towered alkaline, the surface charge of (AS/Fe/AS) became negative charged and consequently, there is no electrostatic repulsion between the positively charged of Cd2+ ions and (AS/Fe/AS) surface, thereby, the adsorption of Cd2+ ions are increased [21], but at very alkaline pH solution, all Cd hydroxides are precipitate and inhibited the adsorption of Cd2+ ions on (AS/Fe/AS) surface, therefore, all the experiments were operated at pH 5.5. The increasing of pH solution after adsorption process may due to increase of the number of hydroxyl ions that released during interaction of nanocomposite magnetic adsorbents (AS/Fe/AS) with H2O.

organic-chemistry-adsorption

FIG. 11. Effect of pH on the adsorption of Cd2+ ions on the AS/Fe/AS nanocomposite.

Effect of contact time

In FIG. 12, the removal efficiency of Cd2+ ions was increased with increasing contact time, this can be attributed to the fact that discussed by Canela et al. [22], who reported that, once Cd2+ ions contacts with AS/ Fe/AS surface, they are removed immediately, but after the available active sites on AS/Fe/AS surface were completely filled, the ions become need longer time to reach other active sites on the surface of the adsorbent. We can say that, in order to get good results, Cd2+ ions should be contact on the surface of AS/Fe/AS nanocomposite for 36 min at least [23]. This result is important, because the equilibrium time, consider one of the most important parameters for an economical wastewater treatment system.

organic-chemistry-contact

FIG. 12. Effect of contact time on the adsorption of Cd2+ ions on the AS/Fe/AS nanocomposite.

Effect of initial concentration: In FIG. 13, it’s observed that, as the initial concentration was varied from 85 to 500 ppm, the corresponding efficiency were varied between 83 to 90.2%, respectively, where, all of pH, time, adsorbent dosage, and the temperature were kept constant. Also, we found that the removal efficiency and Cd2+ ions uptake increases with increasing initial concentration till 300 ppm, and above that concentration such change is not significant [24]. This shows that initial concentration has only a very little effect on adsorption [25].

organic-chemistry-nanocomposite

FIG. 13. Effect of initial Cd2+ ions concentrations on the adsorption of cadmium ions on the AS/Fe/AS nanocomposite.

Kinetics of adsorption

The adsorption kinetics behavior of uptakes Cd2+ ions by AS/Fe/AS nanocomposite, were understudied through the application of pseudo-first and pseudo-second-order kinetic models onto the batch adsorption results [26].

The linear form of the pseudo-first-order model can be expressed as:

image

where k 1 (min−1) is the rate constant of the pseudo-first-order adsorption, and qe and qt(mg g−1) are the adsorption capacities at equilibrium and at time t (min), respectively. The rate constants k 1, qe and correlation coefficients r2 were calculated using the slope and intercept of plots of lg (qe−qt) versus t, as shown in FIG. 14. The pseudo-second-order rate expression is linearly expressed as:

organic-chemistry-first-order

FIG. 14. Pseudo-first-order adsorption of Cd2+ ions on AS/Fe/AS nanocomposites.

image

Anywhere, qe and qt equal the adsorption capacity at equilibrium and at time t (mg g−1), and k 2 (g mg−1 min−1), equal the rate constant of the pseudo-second-order adsorption. From the linear plots of t/qt versus t, we can calculate the rate constants k 2, qe and correlation coefficients r2 (FIG. 15).

organic-chemistry-second-order

FIG. 15. Pseudo-second-order adsorption of Cd2+ ions on AS/Fe/AS nanocomposites.

The parameters of two kinetic models that given in TABLE 1 indicating that, the correlation coefficient (r2) of the pseudo-first-order kinetic model was 0.9211. Whereas, when we applying the pseudo-second-order kinetic model at 25°C, we found that, the correlation coefficient r2 are ranged between 0.9989 to 1, (or almost equal to 1) for all cases, i.e., this means that correlation coefficients (r2) by applying the pseudo-second-order kinetic model, is much higher than the correlation coefficients derived from the pseudo-first-order. We can conclude that the both factors (r2) and qe, revealed that the adsorption of Cd2+ ions onto AS/Fe/AS nanocomposite followed the pseudo-second-order kinetic model, this indicating that the rate-limiting step between Cd2+ ions and the magnetic mesoporous silica nanocomposite is chemical adsorption process [27].

Adsorption isotherm

Generally, adsorption isotherm is the relation between the quantities of adsorbate on the adsorbent as a function of its concentration under equilibrium conditions at constant temperature [28]. Moreover, the adsorption equilibrium is the most important information to understand and analysis the adsorption process [29]. The interaction between adsorbent and adsorbate are described by adsorption isotherms. Generally, adsorption isotherm is the relation between the quantities of adsorbate on the adsorbent as a function of its concentration under equilibrium conditions at constant temperature [28]. Thereby, the adsorption equilibrium is the most important information to understand and analysis the adsorption process. In this work, both models (Langmuir Isotherm and Freundlich Isotherm) were used to describe the relationship between the number of Cd2+ ions adsorbed and its equilibrium concentration in solution at room temperature.

Langmuir isotherm

The Langmuir equation may be written as the following;

image

noting that, we can defined this symbol as the following, Ce (mg/L) is the concentration of Cd2+ions at equilibrium, and Qe (mg/g) means the amount of Cd2+ ions per unit mass of adsorbent (AS/Fe/AS nanocomposites) or means the adsorption capacity at equilibrium, Qm (mg/g) is the Langmuir constants related to the maximum adsorption capacity of Cd2+ ions on AS/Fe/AS nanocomposite surface, where, b (L/mg) is another Langmuir adsorption isotherm constant relates to the energy of adsorption (or rate of adsorption). If we linearity plotting of Ce/Qe versus Ce, we can calculated both Langmuir constants Qm (mg/g) and b (L/mg) from the slope and intercept, respectively [30]. We can also express the fundamental properties of Langmuir isotherm in terms of a constant separation factor without dimensions (KL), which explains the shape and natural of Langmuir isotherm curves as written in the following equation

KL = (1/ (1+bCo), (4)

Somewhere, Co (mg/L) represented the maximum initial concentration of Cd2+ ions and b (L/mg) is Langmuir isotherm constant. From the equation 4, when the parameter KL>1 this means unfavorable adsorption, when 0<KL<1 means, favorable adsorption, when KL=0 this means irreversible adsorption, finally when, KL=1, it means a linear adsorption. The calculated Langmuir constants Qm and KL values are given in TABLE 2. From FIG. 16a and TABLE 2, we shown that the Langmuir constants Qm=0.82 mg/g, KL=0.007 and correlation coefficient (R2)=0.636067. Accordingly, the KL values lay between, 0-1, this indicate a favorable adsorption for all initial Cd2+ions concentrations (Co) and at studied temperatures.

organic-chemistry-nanocomposites

FIG. 16. Langmuir (a) and Freundlich (b) adsorption isotherm of Cd2+ ions onto AS/Fe/AS nanocomposites.

Freundlich adsorption

On the other hand, the linear Freundlich adsorption isotherm can be represented by Equation (5)

image

Where both of kF and n are the Freundlich constants and Ceq is the concentration of Cd2+ ions at equilibrium (mg L-1). From Equation 5, both of kF and n values, can be calculated experimentally from plotting of log Qeq versus log Ceq, thereby, the equilibrium isotherm data that fitted with Freundlich equation are illustrated in FIG. 16b, we found that the Kf and n values, are 2.037 and 3.0029, respectively [31]. We, found also, that the correlation coefficient value (R2) are equal one in case of Freundlich, compared to 0.636067 in case of Langmuir.

In this work, both Langmuir Isotherm and Freundlich Isotherm were applied to describe the relationship between the number of Cd2+ ions adsorbed and its equilibrium concentration in solution at room temperature and the results are presented in TABLE 2.

Mechanism of adsorption process

As shown in FIG. 17, the AS/Fe/AS nanocomposite is composed of three layers, the first one, is the micro silicon oxide layer which located in the core of composite, and covered by second magnetic iron oxide layer, which consisted of zero valent iron and spinning magnetic iron oxide (Fe3O4). The second iron layer possess a variable functional hydroxyl groups, which having an ability as ion exchange and coordination bond, both working together and enhancing the strength of the magnetic layer towered adsorption of heavy metals. The third layer is composed of silicon oxide sheet as semi permeable membrane to adsorb ions under study; such layered give a selectivity to the nanocomposite toward adsorption of heavy metals. The adsorption capacity of Cd2+ ions using silica nanocomposite ranged between 50-73.16 mmol/100 g) as reported in [31], meanwhile, our nanocomposite (AS/Fe/AS) have an adsorption Cd2+ ions affinity of 100 mmol/100 g. This indicating to how the compatibility of our prepared nanocomposite with each other, which increases and enhance their ability to exchange ions, especially in the field of water treatment from heavy elements.

organic-chemistry-ions

FIG. 17. Mechanism of Cd2+ ions adsorption on the AS/Fe/AS nanocomposite.

Novelty of our nanocomposite (AS/Fe/AS)

Mesoporous silica nanoparticles (MSNs), specifically Mobil Crystalline Materials (MCM-41), SiO2, hollow silica and Santa Barbara Amorphous type material (SBA-15), have gained wide popularity over the recent years due to their uniform and tunable pore size, easy independent functionalization of the surface, internal and external pores, high specific surface area and chemical stability, making it a distinctive and promising carrier materials [32]. In the past few years, a lot of works of combination of Fe3O4 and silica frameworks to form a catalytic material were reported. For example, Kevan and coworkers incorporated Fe3O4 into SBA-15 via incipient-wetness impregnation with FeCl3 in ethanol followed by calcinations. The adsorption and degradation of methylene blue and other metal ions like Ni, Zn, Cr ions by a novel catalytic Fe3O4/SiO2 nanocomposite, was reported by Hassan et al. In fact, numbers of similar studies have demonstrated that the silica supported Fe3O4 could present better adsorption performance than traditional materials.

Our product AS/Fe/AS nanocomposite were compared with the other nano-composite in the literature [33-35], and we found that our product AS/Fe/AS nanocomposite are very promising and give removal efficiency of 85-90% at very high Cd2+ ions concentrations reach to 500 ppm, where the other nanocomposite in the literature remove only low pollutant concentrations reach to 50 ppm [33-35].

Conclusion

Magnetic core shell AS/Fe/AS nano-composites was synthesized to remove divalent cadmium ions from contaminated water. The effect of initial concentration, adsorbent dosage, pH and time were studied at a constant temperature of 30°C. Comparing the regression coefficients reveal that the sorption of Cd2+ ions onto AS/Fe/AS nanocomposites can be successfully described by the pseudo-second order kinetic model and Freundlich adsorption isotherm. We found that the Cd2+ ions were successfully removed by adsorption onto AS/Fe/AS nanocomposites. Accordingly, in future we can impregnate our nanocomposites in a suitable matrix to form a polymer nanocomposite.

References

izmir escort izmir escort bursa escort antalya escort izmir escort porno porno izle türk porno eskişehir escort bartın escort burdur escort izmir escort bursa escort porno indir izle escort izmir