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Abstract

New complexes of 6-Amino-4-hydroxy-2-mercaptopyrimidine

Author(s): Sahar I.Mostafa, Fatema A.El-Morsy, Ian S.Butler

6-Amino-4-hydroxy-2-mercaptopyrimidine (Hahmp) complexes, [Zn(ahmp)2], cis-[Mo2O5(ahmp)2], cis-[WO2(ahmp)2] and trans-[UO2(ahmp)2] have been synthesized and characterized on the basis of elemental analysis, thermal and molar conductivity measurements as well as IR, 1H NMR, and mass spectroscopy. Hahmp acts as a mononegative bidentate, coordinates the metal ions through the deprotonated cyclic nitrogen (N-1) and thione sulfur atom.


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