Synthesis and Spectroscopic Properties of Some Hydridophosphine Complexes of Iridium (III)

Author(s): R. N. Pandey and Satyendra Sharma

Mononuclear hydridophosphine complexes of iridium (III) are prepared and characterized by elemental analyses, conductance, magnetic, IR, UV-vis and 1 H NMR spectral data. All complexes are found octahedral and two phosphine ligands are at trans-disposition. The ligand field bands are obscured in some cases. However, electronic spectral data is consistent with assigned structure.

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