44 7460 854 031

All submissions of the EM system will be redirected to Online Manuscript Submission System. Authors are requested to submit articles directly to Online Manuscript Submission System of respective journal.

Abstract

Synthesis and Characterization of New Heterobimetallic [Ca (II)-Ti (IV)]-��-Oxoisopropoxide and its �²-Diketonates

Author(s): Jai Devi and Rajesh Kumar

Thermal condensation of calcium acetate and titani um (IV) isopropoxide resulting the synthesis of new heterobimetallic [Ca (II)-Ti (IV)]- μ -oxoisopropoxide. The characterization and structural elucidation of μ -oxo compound was made by liberated isopr opanol estimation, elemental, spectral (IR, 1 H , 13 C, NMR and mass), thermal analysis, molecular weight data. Many isopropoxy su bstitution reactions of [Ca (II)-Ti (IV)]- μ -oxoisopropoxide compound with β -diketones in different molar ratios (1 : 1-1 : 4) yielded the mono to tetra derivatives [{CaO 2 Ti 2 (OPr i ) 6-n L n } (where n is 1-4 and L = acetylacetonate/benzoylacetonate anion)], respectively of the parent compound and have been characterized by elemental, liberated isopropanol and spectral analysis (IR, 1 H, 13 C NMR). The above studies rev ealed interesting facets in support of plausible structures of parent compound and its β -diketonates.


Share this       
Google Scholar citation report
Citations : 9398

International Journal of Chemical Sciences received 9398 citations as per Google Scholar report

Indexed In

  • Google Scholar
  • Open J Gate
  • China National Knowledge Infrastructure (CNKI)
  • Cosmos IF
  • Geneva Foundation for Medical Education and Research
  • ICMJE

View More